Iranian Journal of  Manufacturing Engineering

Iranian Journal of Manufacturing Engineering

Investigate of the mechanical properties of PP/NBR/SiC nanocomposite in the presence of PP-g-MA compatibilizer for optimizing the modulus of elasticity and impact resistance

Document Type : Original Article

Authors
Faculty of Mechanics and Energy Engineering, Shahid Beheshti University, Tehran, Iran
10.22034/ijme.2025.512467.2066
Abstract
The purpose of this study is to investigate the effect of the components of the polypropylene (PP)/nitrile butadiene rubber (NBR)/silicon carbide (SiC) nanocomposite on the mechanical behavior (modulus of elasticity and impact resistance) in the presence of polypropylene-grafted- maleic anhydride (PP-g-MA) as a compatibilizer. To achieve this, the Box-Behnken Design (BBD) was initially utilized for experiment design and sample selection; The melt blending process was used for sample preparation. Next, a statistical model was developed using the analysis of variance (ANOVA) table based on experimental data, showing a good level of accuracy compared to the actual results. The results obtained from the Response Surface Methodology (RSM) generally show a decrease in the elastic modulus and an increase in impact resistance with the increase of the NBR phase, ranging from 10% to 30% by weight; As the compatibilizer content increases from 3% to 15% by weight, both the elastic modulus and impact resistance continuously improve; Additionally, increasing the SiC nanoparticles from 1% to 5% by weight increases the elastic modulus and improves impact resistance. Optimization of the mechanical properties resulted in values of 273.75 MPa for the elastic modulus and 69.01 J/m for impact resistance. These values were achieved with the optimal composition, which contained 17.62% NBR, 15% PP-g-MA, and 4.47% SiC by weight. Considering the effect of microstructure on the mechanical properties of materials, scanning electron microscopy (SEM) images were used to study the microstructure to confirm the results.
Keywords

[1] Harper CA. Modern plastics handbook. McGraw Hill Professional; 2000 Mar 24.
[2] Greene JP. Automotive plastics and composites: materials and processing. William Andrew; 2021 Jun 23. doi: 10.1016/B978-0-12-818008-2.00004-0
[3] Sin LT, Tueen BS. Plastics and Sustainability: Practical Approaches. Elsevier; 2022 Nov 26. doi: 10.1016/B978-0-12-824489-0.00010-6
[4] Blees MH, Winkelman GB, Balkenende AR, Den Toonder JM. The effect of friction on scratch adhesion testing: application to a sol–gel coating on polypropylene. Thin Solid Films. 2000 Jan 24;359(1):1-3. doi: 10.1016/S0040-6090(99)00729-4
[5] Timsina S. Investigation into mechanical properties to use recycled Polypropylene/Talc composites for car bumper application. Technical Journal. 2019 Jul 1;1(1):54-64. doi: 10.3126/tj.v1i1.27592
[6] Jalil vand AR, Ghasemi E, Karabi M Azizi H. Using devulcanized EPDM in PP/HDPE/ EPDM ternary blend: mechanical properties and morphology. Iranian Polymer Journal. 2007;16(9):637-644.
[7] Deepalekshmi P, Visakh PM, Mathew AP, Chandra AK, Thomas S. Advances in elastomers: their blends and interpenetrating networks-state of art, new challenges and opportunities. Advances in Elastomers I: Blends and Interpenetrating Networks. 2013 Mar 30:1-9. doi: 10.1007/978-3-642-20925-3-1
[8] Elmendorp JJ, Schoolenberg GE. Some wetting and adhesion phenomena in polypropylene composites. Polypropylene Structure, blends and Composites: Volume 3 Composites. 1995: 228-262. doi: 10.1007/978-94-011-0523-1_6
[9] Alipour S, Mostafapour A, Laieghi H, Marzec A. Manufacturing and joining PP/NBR blends in the presence of dual compatibilizer and halloysite nanotubes. Nanomaterials. 2022 Dec 22;13(1):49. doi: 10.3390/nano13010049
[10] Shirvanimoghaddam K, Balaji KV, Yadav R, Zabihi O, Ahmadi M, Adetunji P, Naebe M. Balancing the toughness and strength in polypropylene composites. Composites Part B: Engineering. 2021 Oct 15;223:109121. doi: 10.1016/j.compositesb.2021.109121
[11] Akpan EI, Shen X, Wetzel B, Friedrich K. Design and synthesis of polymer nanocomposites. InPolymer composites with functionalized nanoparticles. Elsevier. 2019 Jan 1:47-83. doi: 10.1016/B978-0-12-814064-2.00002-0
[12] Wang Y, Dong S, Li X, Hong C, Zhang X. Synthesis, properties, and multifarious applications of SiC nanoparticles: A review. Ceramics International. 2022 Apr 1;48(7):8882-913. doi: 10.1016/j.ceramint.2021.12.208
[13] Abraar SM, Rajhu NM, Vardhan TV, Agrawal A, Saxena KK, Savithiri V, Buddhi D, Senthilvel K, Ramesh B. Experimental Investigation on Metallurgical and Mechanical Properties and Wear Behavior of Al5032/SiC Nanocomposites. Materials Research. 2023 Jul 14;26:e20230178. doi: 10.1590/1980-5373-mr-2023-0178
[14] Ye W, Fu J. Study on the impermeability and microstructure of cement mortar blended with silicon carbide nanowhiskers. Case Studies in Construction Materials. 2023 Dec 1;19:e02334. doi: 10.1016/j.cscm.2023.e02334
[15] Khodabandelou M, Aghjeh MK, Khonakdar HA, Mazidi MM. Effect of localization of carbon nanotubes on fracture behavior of un-vulcanized and dynamically vulcanized PP/EPDM/MWCNT blend-nanocomposites. Composites Science and Technology. 2017 Sep 8;149:134-48. doi: 10.1016/j.compscitech.2017.06.003
[16] Guezzout Z, Boublia A, Haddaoui N. Enhancing thermal and mechanical properties of polypropylene-nitrile butadiene rubber nanocomposites through graphene oxide functionalization. Journal of Polymer Research. 2023 Jun;30(6):207. doi: 10.1007/s10965-023-03585
[17] Lim JW, Hassan A, Rahmat AR, Wahit MU. Phase morphology and mechanical properties of rubber-toughened polypropylene nanocomposites: effect of elastomer polarity. Polymer-Plastics Technology and Engineering. 2008 Mar 31;47(4):411-9. doi: 10.1080/03602550801898289
[18] Gulieva TM, Kurbanova NI. Properties of Metal-Containing Nanocomposites Based on Isotactic Polypropylene and Nitrile Butadiene Rubber. High Energy Chemistry. 2023 Dec 57:S320-4. doi: 10.1134/S001814392308012
[19] Hajibeigi M, Nakhaei MR, Rahi A, Naderi G. The optimization of mechanical properties of polypropylene/styrene butadiene rubber/silicon carbide nanocomposites using response surface methodology. Polymer Engineering & Science. 2024 Sep 64(9):4442-55. doi: 10.1002/pen.26859
[20] Yuangyai C, Nembhard HB. Design of experiments: a key to innovation in nanotechnology. InEmerging nanotechnologies for manufacturing. William Andrew Publishing. 2015 Jan 1: 230-254. doi: 10.1016/B978-0-323-28990-0.00008-7
[21] Ashenai Ghasemi F, Daneshpayeh S, Ghasemi I, Ayaz M. An investigation on the Young’s modulus and impact strength of nanocomposites based on polypropylene/linear low-density polyethylene/titan dioxide (PP/LLDPE/TiO 2) using response surface methodology. Polymer Bulletin. 2016 Jun;73:1741-60. doi: 10.1007/s00289-015-1574-2
[22] Bakhtiari A, Ashenai Ghasemi F, Naderi G, Nakhaei MR. An approach to the optimization of mechanical properties of polypropylene/nitrile butadiene rubber/halloysite nanotube/polypropylene‐g‐maleic anhydride nanocomposites using response surface methodology. Polymer Composites. 2020 Jun;41(6):2330-43. doi: 10.1002/pc.25541
[23] Ahmadi A, Arab NM, Naderi G, Nakhaei MR. Multi-response optimization of mechanical properties of laser welds of PP/EPDM/clay nanocomposite using response surface methodology based on desirability approach analysis. Journal of Elastomers & Plastics. 2021 Jun;53(4):323-46. doi: 10.1177/0095244320933979
[24] Mirabzadeh R, Parvaneh V, Ehsani A. Experimental and numerical investigation of the generated heat in polypropylene sheet joints using friction stir welding (FSW). International Journal of Material Forming. 2021 Sep;14:1067-83. doi: 10.1007/s12289-021-01622-y
[25] Liao CZ, Tjong SC. Essential work of fracture study on thermoplastic polyolefin filled with silicon carbide nanoparticles. e-Polymers. 2010 Dec 1;10(1):075. doi: 10.1515/eploy.2010.10.1.822
[26] Wang G, Zhang S, Li T, Xu X, Zhong Q, Chen Y, Deng O, Li Y. Application of response surface methodology for the optimization of lead removal from contaminated soil using chelants. RSC advances. 2015;5(71):58010-8. doi: 10.1039/C5RA06977G
[27] Myers RH, Montgomery DC, Vining GG, Borror CM, Kowalski SM. Response surface methodology: a retrospective and literature survey. Journal of quality technology. 2004 Jan 1;36(1):53-77. doi: 10.1080/00224065.2004.11980252
[28] Paran SM, Naderi G, Ghoreishy MH. Microstructure and mechanical properties of thermoplastic elastomer nanocomposites based on PA6/NBR/HNT. Polymer Composites. 2017 Sep 38:E451-61. doi: 10.1002/pc.23936
[29] Ismail H, Tan BK, Suharty NS, Husseinsyah S, Supri AG. Effects of halloysite nanotubes on the properties of polypropylene/(recycled natural rubber gloves)/(halloysite nanotubes composites). Journal of Vinyl and Additive Technology. 2016 Dec 22(4):487-91. doi: 10.1002/vnl.21473
[30] Li CQ, Zha JW, Long HQ, Wang SJ, Zhang DL, Dang ZM. Mechanical and dielectric properties of graphene incorporated polypropylene nanocomposites using polypropylene-graft-maleic anhydride as a compatibilizer. Composites Science and Technology. 2017 Dec 1;153:111-8. doi: 10.1016/j.compscitech.2017.10.015
[31] Hajibabazadeh S, Razavi Aghjeh MK, Palahang M. Study on the fracture toughness and deformation micro-mechanisms of PP/EPDM/SiO2 ternary blend-nanocomposites. Journal of Composite Materials. 2020 Mar 54(5):591-605. doi: 10.1177/0021998319863475
[32] Hejazi I, Sharif F, Garmabi H. Effect of material and processing parameters on mechanical properties of polypropylene/ethylene–propylene–diene–monomer/clay nanocomposites. Materials & Design. 2011 Aug 1;32(7):3803-9. doi: 10.1016/j.matdes.2011.03.017
[33] Haghnegahdar M, Naderi G, Ghoreishy MH. Fracture toughness and deformation mechanism of un-vulcanized and dynamically vulcanized polypropylene/ethylene propylene diene monomer/graphene nanocomposites. Composites Science and Technology. 2017 Mar 22;141:83-98. doi: 10.1016/j.compscitech.2017.01.015