Iranian Journal of  Manufacturing Engineering

Iranian Journal of Manufacturing Engineering

Investigation of the hot deformation behavior of Ti-48Al-2Cr-2Nb intermetallic with duplex initial microstructure

Document Type : Original Article

Authors
1 Faculty of Materials and Manufacturing Technologies, Malek Ashtar University of Technology, Tehran, Iran
2 Faculty of Metallurgy and Material Engineering, Hamedan University of Technology, Hamedan, Iran
Abstract
The purpose of the present study is to investigate the hot flow behavior of Ti-48Al-2Cr-2Nb intermetallic with duplex initial microstructure. Hot compression tests were conducted at temperatures of 1000, 1050, 1100, and 1150 °C and strain rates of 0.001, 0.01, and 0.1 s-1. The peak stress decreased with increasing deformation temperature and decreasing strain rate. The highest strain rate sensitivity coefficient for hot deformation was 0.33 at 1100°C and strain rate of 0.001 s-1, while the lowest value was below 0.13 in the strain rate range of 0.1 s-1 and temperatures from 1000 to 1100°C. The activation energy was calculated to be 166 kJ/mol, and the stress exponent was 3.4. During hot deformation of this intermetallic at temperatures of 1000 and 1050°C, lamellae bending along with dynamic recrystallization were the dominant softening mechanisms. Increasing the temperature and reducing the strain rate led to an increase in the recrystallization fraction and recrystallized grain size. As the deformation temperature increased to 1100°C, due to approaching the temperature range of the α2/α transformation, the possibility of recrystallization through nucleation decreased, and phase decomposition became the dominant softening mechanism. During deformation at 1150°C, the dominant softening mechanism changed to occur through the formation of shear bands. Based on the energy consumption efficiency criteria, temperature of 1100°C and strain rate of 0.001 s-1 were proposed as the optimal hot deformation conditions for the Ti-48Al-2Cr-2Nb intermetallic with an efficiency of 48.8%.
Keywords

[1] Leyens C, Peters M. Titanium and titanium alloys: fundamentals and applications. Weinheim: Wiley-VCH Verlag GmbH & Co. KGaA; 2003. doi: 10.1002/3527602119
[2] Appel F, Paul JD, Oehring M. Gamma titanium aluminide alloys: science and technology. John Wiley & Sons; 2011 Oct 17. doi: 10.1002/9783527636204
[3] Sauthoff G. Intermetallics. Weinheim: Wiley-VCH; 1995. doi: 10.1002/14356007.e14_e01.pub2
[4] Matthew J, Donachie J. Titanium: a technical guide. 2nd ed. Materials Park, OH: ASM International; 2000. doi: 10.31399/asm.tb.ttg2.9781627082693
[5] Chen YY, Chen YF, Xiao SL, Kong FT, Tian J, Xu LJ. Research on the hot precision processing of TiAl alloys. InMaterials Science Forum 2009 Sep 9 (Vol. 620, pp. 407-412). Trans Tech Publications Ltd. doi: 10.4028/www.scientific.net/MSF.620-622.407
[6] Dieter GE, Kuhn HA, Semiatin SL, editors. Handbook of workability and process design. ASM international; 2003.
[7] Rezaei Ashtiani HR, Shayanpoor AA. Processing workability and artificial neural network of AA1070 to the prediction of hot flow stress. Physics of Metals and Metallography. 2021 Dec;122(13):1426-35. doi: 10.1016/j.jmatprotec.2007.06.071
[8] Li J, Yang X, Zhu Y, Zhang Y, Qiu Y, Sanders Jr RE. Study of thermal compression constitutive relation for 5182-Sc-Zr alloy based on Arrhenius-type and ANN model. Crystals. 2022 Apr 26;12(5):611. doi: 10.3390/cryst12050611
[9] Rezaei Ashtiani HR, Shayanpoor AA. Hot deformation characterization of pure aluminum using artificial neural network (ANN) and processing map considering initial grain size. Metals and Materials International. 2021;27:5017-33. doi: 10.1007/s12540-020-00943-y
[10] Gu YC, Wang LS, Huang X, Song K, Lu SQ, Ding J. Data-driven constitutive model of GH4169 alloy within a synergistic high strain rate and elevated temperature. Archive of Applied Mechanics. 2023 Sep;93(9):3341-58. doi: 10.1007/s00419-023-02442-z
[11] Chen X, Tang B, Liu Y, Xue X, Li L, Kou H, Li J. Dynamic recrystallization behavior of the Ti–48Al–2Cr–2Nb alloy during isothermal hot deformation. Progress in Natural Science: Materials International. 2019 Oct 1;29(5):587-94.doi: 10.1016/j.pnsc.2019.08.004
[12] Usta M, Wolfe H, Duquette DJ, Stoloff NS, Wright RN. Thermo-mechanical grain refinement in gamma (γ) based TiAl intermetallics. Materials Science and Engineering: A. 2003 Oct 25;359(1-2):168-77. doi: 10.1016/S0921-5093(03)00337-X
[13] Wan Z, Sun Y, Hu L, Yu H. Experimental study and numerical simulation of dynamic recrystallization behavior of TiAl-based alloy. Materials & Design. 2017 May 15;122:11-20. doi: 10.1016/j.matdes.2017.02.088
[14] Shih DS, Scarr GK. High-Temperature Deformation Behavior of the γ Alloy Ti-48Ai-2Cr-2Nb. MRS Online Proceedings Library (OPL). 1990 Jan;213:727.
[15] ASTM International. ASTM E209: Standard Practice for Compression Tests of Metallic Materials at Elevated Temperatures with Conventional or Rapid Heating Rates and Strain Rates. West Conshohocken, PA: ASTM International; 2018.
[16] Vander Voort GF. Metallography and Microstructures. Vol. 9. Materials Park, OH: ASM International; 2004. doi: 10.31399/asm.hb.v09.9781627081771
[17] ASTM International. ASTM E112: Standard Test Methods for Determining Average Grain Size. West Conshohocken, PA: ASTM International; 2004.
[18] Cheng L, Chang H, Tang B, Kou H, Li J. Deformation and dynamic recrystallization behavior of a high Nb containing TiAl alloy. Journal of alloys and compounds. 2013 Mar 5;552:363-9. doi: 10.1016/j.jallcom.2012.11.076
[19] Chu Y, Li J, Zhao F, Tang B, Kou H. Flow behavior and constitutive relationship for elevated temperature compressive deformation of a high Nb containing TiAl alloy with (α2+ γ) microstructure. Materials Letters. 2018 Jan 1;210:58-61. doi: 10.1016/j.matlet.2017.08.131
[20] Jiang HT, Zeng SW, Tian SW, Wu B, Zhao AM, Xia ZH. Microstructural Evolution and Dynamic Recrystallization Behavior of β–γ TiAl‐based Alloy during Hot Compression. Advanced Engineering Materials. 2017 Feb;19(2):1600546. doi: 10.1002/adem.201600546
[21] Kong F, Cui N, Chen Y, Wang X, Xiong N. Characterization of hot deformation behavior of as-forged TiAl alloy. Intermetallics. 2014 Dec 1;55:66-72. doi: 10.1016/j.intermet.2014.07.010
[22] Liu B, Liu Y, Li YP, Zhang W, Chiba A. Thermomechanical characterization of β-stabilized Ti–45Al–7Nb–0.4 W–0.15 B alloy. Intermetallics. 2011 Aug 1;19(8):1184-90. doi: 10.1016/j.intermet.2011.03.021
[23] Singh V, Mondal C, Kumar A, Bhattacharjee PP, Ghosal P. High temperature compressive flow behavior and associated microstructural development in a β-stabilized high Nb-containing γ-TiAl based alloy. Journal of Alloys and Compounds. 2019 Jun 5;788:573-85. doi: 10.1016/j.jallcom.2019.02.207
[24] Sokolovsky VS, Stepanov ND, Zherebtsov SV, Nochovnaya NA, Panin PV, Zhilyakova MA, Popov AA, Salishchev GA. Hot deformation behavior and processing maps of B and Gd containing β-solidified TiAl based alloy. Intermetallics. 2018 Mar 1;94:138-51. doi: 10.1016/j.intermet.2019.106521
[25] Hu Q, Wang Y, Lv L, Luo Y, Su L, Liu B. Hot deformation behavior and dynamic recrystallization mechanism of Ti-48Al-2Nb-2Cr alloy with near-γ microstructure. Journal of Alloys and Compounds. 2023 Jun 5;945:169378. doi: 10.1016/j.jallcom.2023.169378
[26] Humphreys FJ, Hatherly M. Recrystallization and Related Annealing Phenomena. 2nd ed. Oxford: Elsevier; 2004.
[27] Navaeilavasani N, Jafarian HR, Arabi H, Park N. Texture analysis and development of ultrafine grained structure during thermo-mechanical treatment in a gamma-TiAl intermetallic. Materials Science and Engineering: A. 2018 Jan 10;711:259-67. doi: 10.1016/j.msea.2017.11.023
[28] Prasad YV, Rao KP, Sasidhar S, editors. Hot working guide: a compendium of processing maps. ASM international; 2015 Aug 1.
[29] Sonboli A, Nematzadeh F, Mojgani A, Nouri A. Construction of constitutive equations, modified dynamic materials model and strain-rate sensitivity coefficient map for investigation of hot and warm working instability of 2205 duplex stainless steel. Iranian Journal of Manufacturing Engineering. 2022 Mar 16;8(12):1-0. [In Persian]
[30] Rezaei Ashtiani H, Mohammadi M. Prediction of hot deformation behavior of 304 stainless steel using Johnson-Cook equation. Iranian Journal of Manufacturing Engineering. 2022 Mar 16;8(12):34-43. (in Persian)
[31] Semiatin SL, Jonas JJ. Formability and Workability of Metals: Plastic Deformation and Workability. Metals Park, OH: ASM International; 1984.
[32] Gupta RK, Murty SN, Pant B, Agarwala V, Sinha PP. Hot workability of γ+ α2 titanium aluminide: Development of processing map and constitutive equations. Materials Science and Engineering: A. 2012 Aug 15;551:169-86.
[33] Appel F, Oehring M, Wagner R. Novel design concepts for gamma-base titanium aluminide alloys. Intermetallics. 2000 Sep 1;8(9-11):1283-312. doi: 10.1016/S0966-9795(00)00036-4
[34] Li M, Li J, Zhou T, Xiao S, Chen Y, Xu L, Hu L, Shi L. The investigation of microstructure evolution, deformation behavior and processing performance of the high niobium containing TiAl alloys. Intermetallics. 2021 Nov 1;138:107336. doi: 10.1016/j.intermet.2021.107336
[35] Fröbel U, Appel F. Hot-workability of gamma-based TiAl alloys during severe torsional deformation. Metallurgical and Materials Transactions A. 2007 Aug;38:1817-32. doi: 10.1007/s11661-007-9203-9
[36] Duan B, Yang Y, He S, Feng Q, Mao L, Zhang X, Jiao L, Lu X, Chen G, Li C. History and development of γ-TiAl alloys and the effect of alloying elements on their phase transformations. Journal of Alloys and Compounds. 2022 Jul 15;909:164811. doi: 10.1016/j.jallcom.2022.164811
[37] Li C, Huang L, Zhao M, Guo S, Li J. Hot deformation behavior and mechanism of a new metastable β titanium alloy Ti–6Cr–5Mo–5V–4Al in single phase region. Materials Science and Engineering: A. 2021 May 13;814:141231. doi: 10.1016/j.msea.2021.141231